Adsorption of SO2 over Alkali Metal Ion-exchanged ZSM-5 zeolites.

Adsorption of Carbon Dioxide on Alkali Metal Exchanged Zeolites

Selective catalytic reduction of nitric oxide by methane over cerium and silver ion-exchanged ZSM-5 zeolites

A new catalyst comprising cerium and silver ion-exchanged ZSM-5 zeolite is reported in this paper, for the reduction of nitric oxide by methane in the presence of excess oxygen. The bi-cation exchanged Ce-Ag-ZSM-5 catalyst was very active for this reaction, while either Ce-ZSM-5 or Ag-ZSM-5 alone showed low activity. The presence of oxygen in the feed gas mixture enhanced the activity of the ca...

Experimental and density functional theory study of the adsorption of N2O on ion-exchanged ZSM-5: part II. The adsorption of N2O on main-group ion-exchanged ZSM-5.

The adsorption and desorption of N2O on main-group ion-exchanged ZSM-5 was studied using temperature-programmed desorption (TPD) and density functional theory (DFT) calculations. TPD experiments were carried out to determine the desorbed temperature Tmax corresponding to the maximum mass intensity of N2O desorption peak and adsorption capacity of N2O on metal-ion-exchanged ZSM-5s. The results i...

Adsorption of carbon monoxide in H-ZSM-5 and Li-ZSM-5 zeolites: an embedded ab initio cluster study

The absorption of carbon monoxide with H-ZSM-5 and metal-substituted Li-ZSM-5 zeolites has been investigated by Ž . using both cluster and embedded cluster approaches at the HFr6–31G d,p level of theory. For the H-ZSM-5 zeolite, the binding energy of CO on a 3T quantum cluster is predicted to be 2.25 kcalrmol for the C-bound complex. The O-bound complex was found to be less stable by about 0.84...

Deep desulfurization of diesel by adsorption over Ni/ZSM-5

Introduction Environmental restriction regarding the quality of transportation fuels and the emissions from them are the most important issues. Because of more stringent regulations and fuel specifications regarding development of better method for deep-desulfurization of fuels are important. There has been recent interest in developing adsorbents for selective desulfurisation by adsorption. Me...